# Carbonate chemistry over a timecourse in pH drift experiments # S. Dudgeon, J. Kubler (CSU) # version: 2018-02-07 # ========================= trial sal_insitu temp_insitu ------------------------- 5 33.9 20 ========================= ID ALK pH_t0 pH_t2 pH_t6 pH_t20 pH_t24 pH_t30 t0_DIC_x_1e06 t2_DIC_x_1e06 t6_DIC_x_1e06 t20_DIC_x_1e06 t24_DIC_x_1e06 t30_DIC_x_1e06 t0_CO2_x_1e06 t2_CO2_x_1e06 t6_CO2_x_1e06 t20_CO2_x_1e06 t24_CO2_x_1e06 t30_CO2_x_1e06 t0_HCO3_x_1e06 t2_HCO3_x_1e06 t6_HCO3_x_1e06 t20_HCO3_x_1e06 t24_HCO3_x_1e06 t30_HCO3_x_1e06 t0_CO3_x_1e06 t2_CO3_x_1e06 t6_CO3_x_1e06 t20_CO3_x_1e06 t24_CO3_x_1e06 t30_CO3_x_1e06 ------------------------- SW-A-1-1 2222.27 8.0042 nd nd nd 8.2442 8.2842 1996.211786 nd nd nd 1860.350428 1834.302894 14.17278188 nd nd nd 7.194062828 6.389582084 1821.01882 nd nd nd 1606.325514 1564.342285 161.0201837 nd nd nd 246.8308512 263.5710267 SW-A-1-2 2222.27 8.0042 nd nd nd 8.1742 8.1942 1996.211786 nd nd nd 1903.628391 1891.56827 14.17278188 nd nd nd 8.817098151 8.323492859 1821.01882 nd nd nd 1675.656542 1656.398934 161.0201837 nd nd nd 219.154751 226.8458434 SW-A-2-1 2222.27 8.0042 nd nd nd 8.2542 8.3342 1996.211786 nd nd nd 1853.926569 1800.461609 14.17278188 nd nd nd 6.985057536 5.495390365 1821.01882 nd nd nd 1595.986887 1509.586068 161.0201837 nd nd nd 250.9546241 285.3801504 SW-A-2-2 2222.27 8.0042 nd nd nd 8.4842 8.5642 1996.211786 nd nd nd 1691.494265 1629.909204 14.17278188 nd nd nd 3.433528141 2.640476716 1821.01882 nd nd nd 1332.293602 1231.804179 161.0201837 nd nd nd 355.7671345 395.4645482 SW-A-3-1 2222.27 8.0042 nd nd nd 8.1742 8.2942 1996.211786 nd nd nd 1903.628391 1827.646279 14.17278188 nd nd nd 8.817098151 6.201214125 1821.01882 nd nd nd 1675.656542 1553.588718 161.0201837 nd nd nd 219.154751 267.8563473 SW-A-3-2 2222.27 8.0042 nd nd nd 8.2242 8.2742 1996.211786 nd nd nd 1873.019052 1840.902234 14.17278188 nd nd nd 7.628571845 6.5829353 1821.01882 nd nd nd 1626.681666 1574.994051 161.0201837 nd nd nd 238.7088142 259.3252476 SW-A-4-1 2208.995 7.829 nd nd nd 8.559 8.679 2061.582744 nd nd nd 1623.246953 1529.142545 22.43186713 nd nd nd 2.669014869 1.772363698 1925.416792 nd nd nd 1230.298018 1076.991256 113.7340851 nd nd nd 390.2799205 450.3789258 SW-A-4-2 2208.995 7.829 nd nd nd 8.589 8.669 2061.582744 nd nd nd 1599.895857 1537.028846 22.43186713 nd nd nd 2.413795858 1.83525555 1925.416792 nd nd nd 1192.229514 1089.822769 113.7340851 nd nd nd 405.2525464 445.3708215 SW-A-5-1 2208.995 7.829 nd nd nd 8.369 8.449 2061.582744 nd nd nd 1764.737621 1706.829828 22.43186713 nd nd nd 4.907838524 3.819046456 1925.416792 nd nd nd 1460.661547 1366.514588 113.7340851 nd nd nd 299.1682354 336.4961936 SW-A-5-2 2208.995 7.829 nd nd nd 8.639 8.739 2061.582744 nd nd nd 1560.669087 1481.889184 22.43186713 nd nd nd 2.035959841 1.433619503 1925.416792 nd nd nd 1128.310263 1000.214697 113.7340851 nd nd nd 430.3228642 480.2408678 SW-A-6-1 2208.995 7.829 nd nd nd 8.529 8.619 2061.582744 nd nd nd 1646.400281 1576.395092 22.43186713 nd nd nd 2.947650014 2.180317205 1925.416792 nd nd nd 1268.046699 1153.928801 113.7340851 nd nd nd 375.4059324 420.2859738 SW-A-6-2 2208.995 7.829 nd nd nd 8.319 8.389 2061.582744 nd nd nd 1799.358794 1750.534951 22.43186713 nd nd nd 5.718196094 4.612950912 1925.416792 nd nd nd 1516.765269 1437.600331 113.7340851 nd nd nd 276.8753287 308.3216687 SW-A-7-1 2223.14 7.6525 nd nd nd 8.5025 8.5725 2139.947695 nd nd nd 1678.287929 1624.125829 35.41903128 nd nd nd 3.237121934 2.569350838 2024.864704 nd nd nd 1310.142061 1221.751107 79.6639605 nd nd nd 364.9087464 399.8053715 SW-A-7-2 2223.14 7.6525 nd nd nd 8.5125 8.5925 2139.947695 nd nd nd 1670.632373 1608.446755 35.41903128 nd nd nd 3.133274803 2.402323794 2024.864704 nd nd nd 1297.650736 1196.164403 79.6639605 nd nd nd 369.848363 409.8800282 SW-A-8-1 2223.14 7.6525 nd nd nd 8.1925 8.2825 2139.947695 nd nd nd 1893.383147 1836.192194 35.41903128 nd nd nd 8.367931579 6.424768249 2024.864704 nd nd nd 1658.736692 1566.81167 79.6639605 nd nd nd 226.2785229 262.9557557 SW-A-8-2 2223.14 7.6525 nd nd nd 8.4925 7.5725 2139.947695 nd nd nd 1685.911754 2166.246019 35.41903128 nd nd nd 3.343971784 43.23238531 2024.864704 nd nd nd 1322.579952 2055.741623 79.6639605 nd nd nd 359.98783 67.27201134 SW-A-9-1 2223.14 7.6525 nd nd nd 8.2225 8.3825 2139.947695 nd nd nd 1874.859556 1767.248575 35.41903128 nd nd nd 7.669713375 4.739430879 2024.864704 nd nd nd 1629.065196 1455.075489 79.6639605 nd nd nd 238.1246468 307.4336551 SW-A-9-2 2223.14 7.6525 nd nd nd 8.3225 8.4025 2139.947695 nd nd nd 1809.259228 1752.846506 35.41903128 nd nd nd 5.696560766 4.453263192 2024.864704 nd nd nd 1523.253082 1431.652758 79.6639605 nd nd nd 280.3095854 316.7404852 A-A-1-1 2440.285 8.0548 nd nd nd 8.4048 8.4148 2171.697206 nd nd nd 1935.361223 1927.531237 13.59803846 nd nd nd 4.88636404 4.736068696 1963.069141 nd nd nd 1579.229145 1566.30857 195.0300265 nd nd nd 351.2457143 356.4865984 A-A-1-2 2440.285 8.0548 nd nd nd 8.3148 8.3548 2171.697206 nd nd nd 2003.433129 1973.734767 13.59803846 nd nd nd 6.437931148 5.702080785 1963.069141 nd nd nd 1691.241624 1642.45204 195.0300265 nd nd nd 305.753574 325.580646 A-A-2-1 2440.285 8.0548 nd nd nd 8.4648 8.4948 2171.697206 nd nd nd 1887.678108 1863.257323 13.59803846 nd nd nd 4.043583142 3.672087415 1963.069141 nd nd nd 1500.464443 1460.065511 195.0300265 nd nd nd 383.170082 399.5197247 A-A-2-2 2440.285 8.0548 nd nd nd 8.3848 8.4448 2171.697206 nd nd nd 1950.869622 1903.754257 13.59803846 nd nd nd 5.199504495 4.309143457 1963.069141 nd nd nd 1604.80138 1527.039544 195.0300265 nd nd nd 340.8687379 372.4055693 A-A-3-1 2440.285 8.0548 nd nd nd 8.4248 8.4548 2171.697206 nd nd nd 1919.652487 1895.737671 13.59803846 nd nd nd 4.589828787 4.174516831 1963.069141 nd nd nd 1553.301696 1513.789705 195.0300265 nd nd nd 361.7609622 377.7734488 A-A-3-2 2440.285 8.0548 nd nd nd 8.3948 8.4248 2171.697206 nd nd nd 1943.141113 1919.652487 13.59803846 nd nd nd 5.040810186 4.589828787 1963.069141 nd nd nd 1592.060896 1553.301696 195.0300265 nd nd nd 346.0394068 361.7609622 A-A-4-1 2439.825 7.8912 nd nd nd 8.2912 8.3512 2254.830322 nd nd nd 2020.107234 1976.04904 21.11205157 nd nd nd 6.908554066 5.76399543 2091.172067 nd nd nd 1718.883694 1646.580466 142.5462028 nd nd nd 294.3149854 323.7045787 A-A-4-2 2439.825 7.8912 nd nd nd 8.3312 8.3612 2254.830322 nd nd nd 1990.970864 1968.503039 21.11205157 nd nd nd 6.125541982 5.590320848 2091.172067 nd nd nd 1671.105435 1634.165604 142.5462028 nd nd nd 313.7398866 328.747114 A-A-5-1 2439.825 7.8912 nd nd nd 8.3712 8.4312 2254.830322 nd nd nd 1960.901716 1914.198047 21.11205157 nd nd nd 5.421235875 4.497410856 2091.172067 nd nd nd 1621.651898 1544.620858 142.5462028 nd nd nd 333.8285824 365.0797786 A-A-5-2 2439.825 7.8912 nd nd nd 8.3812 8.4112 2254.830322 nd nd nd 1953.246188 1929.96629 21.11205157 nd nd nd 5.25663614 4.78873662 2091.172067 nd nd nd 1609.041508 1570.653125 142.5462028 nd nd nd 338.9480434 354.524429 A-A-6-1 2439.825 7.8912 nd nd nd 8.3412 8.3712 2254.830322 nd nd nd 1983.538653 1960.901716 21.11205157 nd nd nd 5.942366197 5.421235875 2091.172067 nd nd nd 1658.894406 1621.651898 142.5462028 nd nd nd 318.7018806 333.8285824 A-A-6-2 2439.825 7.8912 nd nd nd 8.5012 8.5012 2254.830322 nd nd nd 1857.624891 1857.624891 21.11205157 nd nd nd 3.596088931 3.596088931 2091.172067 nd nd nd 1451.074648 1451.074648 142.5462028 nd nd nd 402.9541547 402.9541547 A-A-7-1 2453.92 7.6964 nd nd nd 8.3764 8.4464 2349.72999 nd nd nd 1968.982581 1913.89468 35.06905494 nd nd nd 5.367955946 4.313087436 2218.111602 nd nd nd 1625.055785 1534.078535 96.54933282 nd nd nd 338.5588397 375.503057 A-A-7-2 2453.92 7.6964 nd nd nd 8.3364 8.3864 2349.72999 nd nd nd 1999.304676 1961.264507 35.06905494 nd nd nd 6.066677437 5.204681365 2218.111602 nd nd nd 1674.982351 1612.328304 96.54933282 nd nd nd 318.2556474 343.7315223 A-A-8-1 2453.92 7.6964 nd nd nd 8.3664 8.4164 2349.72999 nd nd nd 1976.646755 1937.799116 35.06905494 nd nd nd 5.535687911 4.74059536 2218.111602 nd nd nd 1637.687102 1573.592287 96.54933282 nd nd nd 333.4239654 359.4662339 A-A-8-2 2453.92 7.6964 nd nd nd 8.4064 8.4364 2349.72999 nd nd nd 1945.671503 1921.90929 35.06905494 nd nd nd 4.89109966 4.451681928 2218.111602 nd nd nd 1586.59413 1547.331823 96.54933282 nd nd nd 354.186274 370.1257847 A-A-9-1 2453.92 7.6964 nd nd nd 8.4564 8.5064 2349.72999 nd nd nd 1905.835566 1864.927315 35.06905494 nd nd nd 4.178280643 3.558041532 2218.111602 nd nd nd 1520.746894 1453.015825 96.54933282 nd nd nd 380.9103922 408.3534487 A-A-9-2 2453.92 7.6964 nd nd nd 8.2764 8.3464 2349.72999 nd nd nd 2043.026738 1991.808873 35.06905494 nd nd nd 7.263737949 5.884941513 2218.111602 nd nd nd 1746.704741 1662.652471 96.54933282 nd nd nd 289.058259 323.2714607 E-A-1-1 2635.7 8.02385 nd nd nd 7.96385 7.92385 2370.152438 nd nd nd 2403.433188 2424.343207 16.02847751 nd nd nd 18.8472319 20.96599372 2154.773388 nd nd nd 2206.769156 2238.848892 199.3505723 nd nd nd 177.8167994 164.5283211 E-A-1-2 2635.7 8.02385 nd nd nd 7.94385 7.93385 2370.152438 nd nd nd 2414.011859 2419.208035 16.02847751 nd nd nd 19.88119381 20.41709502 2154.773388 nd nd nd 2223.063101 2231.019062 199.3505723 nd nd nd 171.067565 167.7718775 E-A-2-1 2635.7 8.02385 nd nd nd 8.14385 8.13385 2370.152438 nd nd nd 2296.228988 2302.776225 16.02847751 nd nd nd 11.49079043 11.81969434 2154.773388 nd nd nd 2036.381933 2046.98932 199.3505723 nd nd nd 248.3562644 243.9672104 E-A-2-2 2635.7 8.02385 nd nd nd 8.19385 8.21385 2370.152438 nd nd nd 2262.426066 2248.408878 16.02847751 nd nd nd 9.964336937 9.405653663 2154.773388 nd nd nd 1981.334198 1958.386082 199.3505723 nd nd nd 271.1275309 280.6171423 E-A-3-1 2635.7 8.02385 nd nd nd 8.02385 8.02385 2370.152438 nd nd nd 2370.152438 2370.152438 16.02847751 nd nd nd 16.02847751 16.02847751 2154.773388 nd nd nd 2154.773388 2154.773388 199.3505723 nd nd nd 199.3505723 199.3505723 E-A-3-2 2635.7 8.02385 nd nd nd 8.20385 8.21385 2370.152438 nd nd nd 2255.452716 2248.408878 16.02847751 nd nd nd 9.681453158 9.405653663 2154.773388 nd nd nd 1969.925852 1958.386082 199.3505723 nd nd nd 275.8454109 280.6171423 E-A-4-1 2655.375 7.87965 nd nd nd 8.09965 8.07965 2465.034828 nd nd nd 2342.63103 2355.100919 23.73564367 nd nd nd 13.10909456 13.85786356 2289.340254 nd nd nd 2098.3698 2118.38851 151.9589305 nd nd nd 231.1521358 222.854545 E-A-4-2 2655.375 7.87965 nd nd nd 7.96965 7.94965 2465.034828 nd nd nd 2418.754608 2429.467648 23.73564367 nd nd nd 18.69909956 19.7264081 2289.340254 nd nd nd 2218.860634 2235.410799 151.9589305 nd nd nd 181.1948745 174.3304408 E-A-5-1 2655.375 7.87965 nd nd nd 8.06965 8.07965 2465.034828 nd nd nd 2361.230215 2355.100919 23.73564367 nd nd nd 14.24629402 13.85786356 2289.340254 nd nd nd 2128.194097 2118.38851 151.9589305 nd nd nd 218.7898234 222.854545 E-A-5-2 2655.375 7.87965 nd nd nd 8.00965 7.95965 2465.034828 nd nd nd 2396.552239 2424.142856 23.73564367 nd nd nd 16.78733068 19.20657646 2289.340254 nd nd nd 2184.192826 2227.200373 151.9589305 nd nd nd 195.5720823 177.7359067 E-A-6-1 2655.375 7.87965 nd nd nd 8.04965 7.91965 2465.034828 nd nd nd 2373.279314 2445.069388 23.73564367 nd nd nd 15.05231798 21.36287847 2289.340254 nd nd nd 2147.398845 2259.275023 151.9589305 nd nd nd 210.8281504 164.4314871 E-A-6-2 2655.375 7.87965 nd nd nd 8.00965 7.92965 2465.034828 nd nd nd 2396.552239 2439.930075 23.73564367 nd nd nd 16.78733068 20.80426782 2289.340254 nd nd nd 2184.192826 2251.447203 151.9589305 nd nd nd 195.5720823 167.6786044 E-A-7-1 2656.855 7.66405 nd nd nd 7.95405 7.85405 2560.361706 nd nd nd 2428.522952 2478.748134 41.24181989 nd nd nd 19.50731106 25.39164566 2421.291918 nd nd nd 2233.09264 2308.873717 97.82796869 nd nd nd 175.9230005 144.4827714 E-A-7-2 2656.855 7.66405 nd nd nd 7.86405 7.54405 2560.361706 nd nd nd 2473.983778 2605.670896 41.24181989 nd nd nd 24.73814832 55.55708597 2421.291918 nd nd nd 2301.847354 2474.279686 97.82796869 nd nd nd 147.3982759 75.83412378 E-A-8-1 2656.855 7.66405 nd nd nd 7.71405 7.31405 2560.361706 nd nd nd 2540.316783 2689.322271 41.24181989 nd nd nd 36.36321038 97.09475369 2421.291918 nd nd nd 2395.364173 2546.273765 97.82796869 nd nd nd 108.5893999 45.9537523 E-A-8-2 2656.855 7.66405 nd nd nd 7.81405 7.59405 2560.361706 nd nd nd 2497.279036 2587.175342 41.24181989 nd nd nd 28.1661466 49.10331801 2421.291918 nd nd nd 2335.805983 2453.692697 97.82796869 nd nd nd 133.3069064 84.37932636 E-A-9-1 2656.855 7.66405 nd nd nd 7.81405 7.63405 2560.361706 nd nd nd 2497.279036 2572.009986 41.24181989 nd nd nd 28.1661466 44.4546119 2421.291918 nd nd nd 2335.805983 2435.713225 97.82796869 nd nd nd 133.3069064 91.84214912 E-A-9-2 2656.855 7.66405 nd nd nd 7.81405 7.60405 2560.361706 nd nd nd 2497.279036 2583.419013 41.24181989 nd nd nd 28.1661466 47.90022452 2421.291918 nd nd nd 2335.805983 2449.327621 97.82796869 nd nd nd 133.3069064 86.19116753 SW-NA-380-1 2230.06 8.0042 nd nd nd 7.5742 7.5742 2003.467997 nd nd nd 2172.543356 2172.543356 14.22429981 nd nd nd 43.18678133 43.18678133 1827.638207 nd nd nd 2061.627358 2061.627358 161.6054906 nd nd nd 67.72921661 67.72921661 SW-NA-380-2 2214.48 8.0042 nd nd nd 7.5842 7.5742 1988.955575 nd nd nd 2153.929083 2157.137392 14.12126395 nd nd nd 41.83068223 42.88053473 1814.399434 nd nd nd 2043.404186 2047.007923 160.4348769 nd nd nd 68.69421456 67.24893441 SW-NA-540-1 2208.68 7.8284 nd nd nd 7.7284 7.7284 2061.521 nd nd nd 2099.405982 2099.405982 22.46357959 nd nd nd 29.04687221 29.04687221 1925.476816 nd nd nd 1977.69222 1977.69222 113.5806049 nd nd nd 92.66689016 92.66689016 SW-NA-540-2 2209.31 7.8296 nd nd nd 7.7296 7.7296 2061.644275 nd nd nd 2099.585492 2099.585492 22.40019437 nd nd nd 28.96676844 28.96676844 1925.356334 nd nd nd 1977.695287 1977.695287 113.887747 nd nd nd 92.92343643 92.92343643 SW-NA-700-1 2221.56 7.6558 nd nd nd 7.5558 7.5658 2137.283207 nd nd nd 2170.012668 2166.826814 35.10158237 nd nd nd 45.02282202 43.9235412 2022.022695 nd nd nd 2060.11775 2056.63242 80.15892963 nd nd nd 64.87209562 66.27085308 SW-NA-700-2 2224.72 7.6492 nd nd nd 7.5292 7.5292 2142.610525 nd nd nd 2181.559059 2181.559059 35.73915796 nd nd nd 48.14372208 48.14372208 2027.699748 nd nd nd 2072.0441 2072.0441 79.17161984 nd nd nd 61.37123713 61.37123713 A-NA-380-1 2439.37 8.0545 nd nd nd 7.9845 8.0045 2171.021127 nd nd nd 2208.738499 2198.276831 13.60398349 nd nd nd 16.46287018 15.59584079 1962.571226 nd nd nd 2021.458755 2005.248149 194.8459176 nd nd nd 170.8168733 177.4328415 A-NA-380-2 2441.2 8.0551 nd nd nd 7.9851 7.9951 2172.373131 nd nd nd 2210.138527 2204.931955 13.59209316 nd nd nd 16.44897288 16.0105145 1963.566769 nd nd nd 2022.544639 2014.487697 195.2142683 nd nd nd 171.1449146 174.4337441 A-NA-540-1 2439.9 7.8934 nd nd nd 7.8334 7.8534 2253.881459 nd nd nd 2280.793063 2272.027108 20.99078947 nd nd nd 24.55580868 23.31058402 2089.720023 nd nd nd 2129.185854 2116.471796 143.170647 nd nd nd 127.0514002 132.2447284 A-NA-540-2 2439.75 7.889 nd nd nd 7.829 7.839 2255.776521 nd nd nd 2282.5516 2278.215076 21.2339474 nd nd nd 24.83620624 24.19965031 2092.618538 nd nd nd 2131.790825 2125.535787 141.9240356 nd nd nd 125.9245687 128.4796382 A-NA-700-1 2455.03 7.699 nd nd nd 7.629 7.659 2349.825474 nd nd nd 2375.653448 2364.759128 34.85565518 nd nd nd 41.5497829 38.5463659 2217.852102 nd nd nd 2250.236112 2236.880434 97.11771712 nd nd nd 83.86755332 89.33232849 A-NA-700-2 2452.81 7.6938 nd nd nd 7.6238 7.6438 2349.631553 nd nd nd 2375.335543 2368.131778 35.28364684 nd nd nd 42.05345044 40.00503233 2218.363943 nd nd nd 2250.406461 2241.681753 95.98396387 nd nd nd 82.87563129 86.44499238 E-NA-380-1 2635.59 8.0255 nd nd nd 7.9855 7.9955 2369.101469 nd nd nd 2391.592888 2386.069169 15.95591698 nd nd nd 17.78191502 17.30869683 2153.183778 nd nd nd 2188.456213 2179.835405 199.9617748 nd nd nd 185.3547607 188.9250673 E-NA-380-2 2635.81 8.0222 nd nd nd 7.9822 7.9922 2371.201632 nd nd nd 2393.60713 2388.10458 16.10133307 nd nd nd 17.94214524 17.46509758 2156.359492 nd nd nd 2191.460762 2182.882442 198.7408068 nd nd nd 184.204223 187.7570405 E-NA-540-1 2654.08 7.8783 nd nd nd 7.8283 7.8383 2464.461374 nd nd nd 2488.114065 2483.489659 23.80784293 nd nd nd 27.11851505 26.4246187 2289.177031 nd nd nd 2323.941738 2317.224226 151.4765005 nd nd nd 137.053812 139.8408142 E-NA-540-2 2656.67 7.881 nd nd nd 7.821 7.831 2465.606756 nd nd nd 2493.940623 2489.349997 23.66363177 nd nd nd 27.66306877 26.95639087 2289.500431 nd nd nd 2331.093468 2324.454642 152.4426933 nd nd nd 135.1840866 137.9389639 E-NA-700-1 2657.86 7.6629 nd nd nd 7.6029 7.6129 2561.796486 nd nd nd 2584.84256 2581.065312 41.37675785 nd nd nd 48.05557296 46.87657258 2422.790091 nd nd nd 2450.77302 2446.33079 97.6296365 nd nd nd 86.01396626 87.85794987 E-NA-700-2 2655.85 7.6652 nd nd nd 7.6052 7.6052 2558.926795 nd nd nd 2581.995438 2581.995438 41.10729145 nd nd nd 47.74534593 47.74534593 2419.792873 nd nd nd 2447.881417 2447.881417 98.02663096 nd nd nd 86.36867536 86.36867536